表5-1~表5—18分别列出了九种工艺在电流效率为100%时的镀层厚度和镀层质量数据,这九种镀层分别是氰化镀铜(表5-1、表5-2)、酸性硫酸盐镀铜(表5—3、表5—4)、镍镀层(表5-5、表5-6)、镀银层(表5—7、表5—8)、酸性镀锡(表5-9、表5-10)、碱性镀锡(表5一ll、表5—12)、镀锌层(表5—13、表5—14)、氰化镀黄铜(表5-15、表5—16)和氰化镀青铜(表5-17、表5—18)。表5—19提供了镀层厚度与质量换算数据,表5—20提供了各种镀液体积电流密度数据,而表5—21、表5-22提供了镀铬溶液在不同温度下的电流效率及沉积率。 表5-1 氰化镀铜电流效率l00%时的镀层厚度 /μm 电流密度 /A.dm-2 t/min | 1.O | 1.5 | 2.O | 2.5 | 3.O | 3.5 | 4.O | 5.O | 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 | 0.44 0.89 1.33 1.77 2.21 2.66 3.10 3.54 2.98 4.43 4.87 5.31 5.75 6.20 6.64 7.O8 7.52 7.97 8.41 8.85 | 0.66 1.33 1.99 2.66 3.32 3.98 4.65 5.31 5.98 6.64 7.30 7.97 8.63 9.29 9.96 10.62 11.29 11.95 12.61 13.28 | 0.89 1.77 2.66 3.54 4.43 5.31 6.20 7.O8 7.79 8.85 9.74 10.62 11.51 12.39 13.28 14.16 15.O5 15.93 16.82 17.70 | 1.11 2.21 3.32 4.43 5.53 6.64 7.75 8.85 9.96 11.O7 12.17 13.28 14.38 15.49 16.60 17.70 18.81 19.92 21.O2 22.13 | 1.33 2.66 3.98 5.3l 6.64 7.97 9.29 10.62 11.95 13.28 14.61 15.93 17.26 18.59 19.92 21.25 22:57 23.90 25.23 26.56 | 1.55 3.10 4.65 6.20 7.75 9.29 10.84 12.39 13.94 15.49 17.04 18.59 20.14 21.69 23.24 24.79 26.34 27.88 29.43 30.98 | 1.77 3.54 5.31 7.08 8.85 10.62 12.39 14.16 15.93 17.70 19.48 21.25 23.O2 24.79 26.56 28.33 30.10 31.87 33.64 35.41 | 2.21 4.43 6.64 8.85 11.07 13.28 15.49 17.70 19.92 22.13 24.34 26.56 28.77 30.98 33.20 35.41 37.62 39.84 42.O5 44.26 |
续表 电流密度 A·dm-2 t/min | 1.O | 1.5 | 2.O | 2.5 | 3.O | 3.5 | 4.0 | 5.O | 22 24 25 26 28 30 32 34 35 36 38 40 45 | 9.74 10.62 11.07 11.51 12.39 13.28 14.16 15.05 15.49 15.93 16.82 17.70 19.92 | 14.16 15.93 16.60 17.26 18.59 19.92 21.25 22.57 23.24 Z3.90 25.23 26.56 29.88 | 19.47 21.25 22.13 23.02 24.79 26.56 28.33 30.10 30.98 31.97 33.64 35.41 39.84 | 24.34 26.56 27.66 28.77 30.98 33.20 35.41 37.62 38.73 39.84 42.O5 44.26 49.79 | 29.21 31.87 33.20 34.52 37.18 39.84 42,49 45.17 46.47 47.80 50.46 53.11 59.75 | 34.08 37.18 38.73 40.38 43.38 46.47 49.57 52.67 54.22 55.77 58.87 61.97 69.71 | 38.95 42.49 44.26 46.O3 19.57 53.11 56.66 60.20 61.97 63.74 67.28 70.82 79.67 | 48.69 53.11 55.33 57.54 61.97 66.39 70.82 75.24 77.46 79.67 84.10 88.52 99.59 |
表5-2氰化镀铜电流效率l00%时的镀层质量 /g·m-2 电流密度 A·dm-2 t/min | 1.O | 1.5 | 2.O | 2.5 | 3.O | 3.5 | 4.0 | 5.O | 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 22 24 | 3.95 7.91 11.86 15.81 19.76 23.72 27.67 31.62 35,57 39.53 43.48 47.43 51.38 55.34 59.29 63.24 67.19 71.15 75.10 79.O5 86.96 94.86 | 5.93 11.86 17.79 23.72 29.64 35.57 41.50 47.43 53.36 59.29 65.22 71.15 77.07 83.O0 88.93 94.86 100.79 106.72 112.65 118.58 130.43 142.29 | 7.9l 15.81 23.72 31.62 39.53 47.43 55.34 63.24 71.15 79.O5 86.96 94.86 102.77 110.67 118.58 126.48 134.39 142.29 150.20 158.10 173.91 189.72 | 9.88 19.76 29.64 39.53 49.41 59.29 69.17 79.O5 88.93 98.81 108.69 118.58 128.46 138.34 148.22 158.10 167.98 177.86 187.74 197.63 217.39 237.15 | 11.86 23.72 35.57 47.43 59.29 71.15 83.O0 94.86 10fi.72 118.58 130.43 142.29 154.14 166.Ol 177.86 189.72 201.58 213.44 225.29 237.15 260.87 284.58 | 13.83 27.67 41.50 55.34 69.17 83.O0 96.84 110.67 124.51 138.34 152.17 166.01 179.84 193.67 207.51 221.34 235.18 249.01 262.84 276.68 304.35 332.01 | 15.81 31.62 47.43 63.24 79.O5 94.86 110.67 126.48 142.29 158.10 173.91 189.72 205.53 221.34 237.15 252.96 268.77 284.58 300.39 316.20 347.82 379.44 | 19.76 39.53 59.29 79.01 98.8l 118.58 138.34 158.10 177.86 197.63 217.39 237.15 256.92 276.68 296.44 316.20 335.97 355.73 375.49 395.25 434.78 474.30 |
续表 电流密度 A·dm-2 t/min | 1.0 | 1.5 | 2.O | 2.5 | 3.O | 3.5 | 4.O | 5.O | 25 26 28 30 32 34 35 36 38 40 45 | 98.81 102.77 110.67 118.58 126.48 134.39 138.34 142.19 150.20 158.10 177.86 | 148.22 154.15 166.Ol 177.86 189.72 201.58 207.51 213.44 225.29 237.15 266.80 | 197.63 205.53 221.34 237.15 252.97 268.77 276.68 284.58 300.39 316.20 355.73 | 247.03 256.91 276.68 296.44 316.20 335.97 345.85 355.73 375.49 395.25 444.66 | 296.44 308.30 332.01 355.73 379.44 403.16 415.O2 426.87 450.59 474.30 533.58 | 345.85 359.68 387.35 415.02 422.68 470.35 484.19 498.02 525.69 553.36 622.53 | 395.25 41L06 442.68 474.30 505.92 537.54 553.36 569.16 600.78 632.40 711.45 | 494.07 513.83 553.35 592.88 632.41 671.93 691.69 711.46 750.98 790.51 889.32 |
表5-3酸性硫酸盐镀铜电流效率100%时的镀层厚度 /μm 电流密度 A·dm-2 t/min | 1.0 | 1.5 | 2.O | 2.5 | 3.O | 3.5 | 4.0 | 5.0 | 1 2 3 4 5 6 7 8 9 10 1l 12 13 14 15 16 17 18 19 20 22 24 25 26 | 0.22 0.44 0.66 0.89 1.11 1.33 1.60 1.77 1.99 2.21 2.43 2.66 2.88 3.10 3.32 3.54 3.76 3.98 4.20 4.43 4.87 5.31 5.53 5.75 | 0.33 0.66 1.O0 1.33 1.66 1.99 2.32 2.66 2.99 3.32 3.65 3.98 4.32 4.65 4.98 5.31 5.64 5.98 6.31 6.64 7.30 7.97 8.30 8.63 | 0.44 0.89 1.33 1.77 2.21 2.66 3.10 3.54 3.89 4.43 4.87 5.31 5.75 6.20 6.64 7.O8 7.52 7.97 8.41 8.85 9.74 10.62 11.07 11.51 | 0.55 1.11 1.66 2.21 2.77 3.32 3.87 4.43 4.98 5.53 6.09 6.64 7.19 7.75 8.30 8.85 8.41 9.96 10.51 11.07 12.17 13.28 13.83 14.38 | 0.66 1.33 1.99 2.66 3.32 3.98 4.65 5.31 5.98 6.64 7.30 7.97 8.63 9.29 9.96 10.62 11.29 11.95 12.61 13.28 14.61 15.93 16.60 17.26 | 0.77 1.55 2.32 3.10 3.87 4.65 5.42 6.20 6.97 7.75 8.52 9.29 10.17 10.84 11.62 12.39 13.17 13.94 14.72 15.49 17.04 18.59 19.36 20.14 | 0.89 1.77 2.66 3.54 4.43 5.31 6.20 7.O8 7.97 8.85 9.74 10.62 11.51 12.39 13.28 14.16 15.O5 15.93 16.82 17.70 19.47 21.25 22.13 23.O2 | 1.11 2.21 3.32 4.43 5.53 6.64 7.75 8.85 9.96 11.07 12.17 13.28 14.38 15.49 16.60 17.70 18.81 19.92 21.O2 22.13 24.34 26.56 27.66 28.77 |
续表 电流密度 A·dm-2 t/min | 1.0 | 1.5 | 2.0 | 2.5 | 3.O | 3.5 | 4.0 | 5.O | 28 30 32 34 35 36 38 40 45 | 6.20 6.64 7.O8 7.52 7.75 7.97 8.41 8.85 9.96 | 9.29 9.96 10.62 11.29 11.62 11.75 12.61 13.28 14.94 | 12.39 13.28 14.16 15.O5 15.49 15.93 16.82 17.70 19.92 | 15.49 16.60 17.70 18.81 19.36 19.92 21.O2 22.13 24.90 | 18.59 19.92 21.25 22.57 23.24 23.90 25.23 26.56 29.88 | 21.69 23.24 24.79 26.34 27.11 27.88 29.43 30.98 34.86 | 24.79 26.56 28.33 30.10 30.98 31.87 33.64 35.41 39.84 | 30.98 33.20 35.41 37.62 38.73 39.84 42.O5 44.26 49.79 |
表5-4酸性硫酸盐镀铜电流效率100%时的镀层质量 /g·m-2 电流密度 A·dm-2 t/min | 1.O | 1.5 | 2.0 | 2.5 | 3.0 | 3.5 | 4.0 | 5.0 | l 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 22 24 25 26 28 30 | 1.98 3.95 5.93 7.91 9.88 11.96 13.83 15.81 17.79 19.76 21.74 23.72 25.69 27.67 29.64 31.62 33.60 35.57 37.55 39.53 43.48 47.43 49.41 51.38 55.34 59.29 | 2.96 5.93 8.89 11.86 14.82 17.79 20.75 23.73 26.68 29.64 32.61 35.57 38.54 41.50 44.47 47.43 50.39 53.36 56.32 59.29 65.22 71.15 74.11 77.O7 83.O0 88.93 | 3.95 7.91 11.86 15.81 19.76 23.72 27.67 31.62 35.57 39.53 43.48 47.43 51.38 55.34 59.29 63.24 67.19 71.15 75.10 79.O5 86.96 94.86 98.81 102.77 110.67 118.58 | 4.94 9.88 14.82 19.76 24.70 29.64 34.58 39.53 44.47 49.41 54.35 59.29 64.23 69.17 74.11 79.O5 83.99 88.93 93.87 98.81 108.69 118.58 123.52 128.46 138.34 148.22 | 5.93 11.86 17.79 23.79 29.64 35.57 41.50 47.43 53.36 59.29 65.22 71.15 77.07 83.00 88.93 94.86 100.79 106.72 112.65 118.58 130.43 142.29 148.22 154.15 166.Ol 177.86 | 6.92 13.83 20.75 27.67 34.58 41.50 48.42 55.34 62.25 69.17 76.09 83.00 89.92 96.84 103.75 110.67 117.59 124.50 131.42 138.34 152.17 166.Ol 172.92 179.84 193.67 207.51 | 7.91 15.81 23.72 31.62 39.53 47.43 55.34 63.24 71.15 79.O5 86.96 94.86 102.77 110.67 118.58 126.48 134.39 142.29 150.20 158.10 173.91 173.91 197.63 205.53 221.34 237.15 | 9.88 19.76 29.64 39.53 49.41 59.29 69.17 79.05 88.93 98.81 108.69 118.58 128.46 138.34 148.22 158.10 167.98 177.86 187.75 197.63 217.39 217.39 247.03 256.91 276.68 296.44 |
续表 电流密度 A·dm-2 t/min | 1.0 | 1_5 | 2.O | 2.5 | 3.O | 3.5 | 4.O | 5.O | 32 34 35 36 38 40 45 | 63.24 67.19 69.17 71.15 75.10 79.O5 88.93 | 94.86 100.79 103.75 106.72 112.65 118.58 133.40 | 126.48 134.39 138.34 142.29 150.20 158.10 177.86 | 158.10 167.98 172.92 177.86 187.75 197.63 222.33 | 189.72 201.58 207.51 213.44 225.75 237.15 266.80 | 221.34 235.18 242.09 249.01 262.84 276.68 311.26 | 252.96 268.77 276.68 284.58 300.39 316.20 355.73 | 316.20 335.97 345.85 355.73 375.49 395.25 444.66 |
表5-5 镍镀层电流效率100%时的镀层厚度 /μm 电流密度 A·dm-2 t/min | 1.O | 1.5 | 2.O | 2.5 | 3.O | 4.5 | 5.O | 6.O | 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 22 24 25 26 28 30 32 34 35 | 0.21 0.41 0.62 0.82 1.O3 1.23 1.44 1.64 1.85 2.O5 2.26 2.46 2.67 2.87 3.O8 3.28 3.49 3.69 3.90 4.10 4.51 4.92 5.13 5.33 5.74 6.15 6.56 6.97 7.18 | 0.31 0.62 0.92 1.23 1.54 1.85 2.15 2.46 2.77 3.O8 3.38 3.69 4.O0 4.31 4.61 4.92 5.23 5.54 5.84 6.15 6.77 7.38 7.69 8.O0 8.61 9.23 9.84 10.46 10.76 | 0.41 0,82 1.23 1.64 2.O5 2.46 2.87 3.28 3.69 4.10 4.51 4.92 5.33 5.74 6.15 6.56 6.97 7.38 7.79 8.20 9.O2 9.84 10.25 10.66 11.48 12.30 13.12 13.94 14.35 | 0.51 1.03 1.54 2.O5 2.56 3.O8 3.59 4.10 4.61 5.13 5.64 6.15 6.66 7.18 7.69 8.20 8.71 9.23 9.74 10.25 11.28 12.30 12.81 13.33 14.35 15.38 16.40 17.43 18.94 | 0.62 1.23 1.85 2.46 3.O8 3.69 4.31 4.92 5.54 6.15 6.77 7.38 8.OO 8.61 9.23 9.84 10.46 11.07 11.69 12.30 13.53 14.76 15.38 15.99 17.22 18.45 19.68 20.91 21.53 | 0.82 1.64 2.46 3.28 4.10 4.92 5.74 6.56 7.38 8.20 9.02 9.84 10.66 11.48 12.30 13.12 13.94 14.76 15.58 16.40 18.04 19.68 20.50 21.32 22.96 24.60 26.24 27.88 28.79 | 1.O3 2.O5 3.O8 4.10 5.13 6.15 7.18 8.20 9.23 10.25 11.28 12.30 13.33 14.35 15.38 16.40 17.43 18.45 19.45 20.50 22.55 24.60 25.63 26.65 28.70 30.75 32.80 34.85 35.88 | 1.23 2.46 2.69 4.92 6.15 7.38 8.61 9.84 11.07 12.30 13.53 14.76 15.99 17.22 18.45 19.68 20.91 22.14 23.37 24.60 27.06 29.52 30.75 31.98 34.44 36.90 39.36 41.82 43.O5 |
续表 电流密度 A·dm-2 t/min | 1.0 | 1.5 | 2.0 | 2.5 | 3.0 | 4.5 | 5.O | 6.O | 36 38 40 45 | 7.38 7.79 8.20 9.23 | 11.07 11.69 12.30 13.84 | 14.76 15.58 16.40 18.45 | 18.45 19.48 20.50 23.O6 | 22.14 23.37 24.60 27.68 | 29.52 31.16 32.80 36.90 | 36.90 38.95 41.OO 46.13 | 44.28 46.74 49.20 55.35 |
表5-6镍镀层电流效率100%时的镀层质量 /g·m-2 电流密度 A·dm-2 t/min | 1.O | 1.5 | 2.O | Z.5 | 3.0 | 4.0 | 5.O | 6.0 | 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 22 24 25 26 28 30 32 34 35 36 38 40 45 | 1.82 3.65 5.47 7.30 9.12 10.95 12.77 14.60 16.42 18.25 20.O7 21.89 23.72 25.54 27.37 29.19 31.O2 32.84 36.67 36.49 40.14 43.79 45.16 47.44 51.09 54.74 58.39 62.04 63.86 65.68 69.33 72.98 82.11 | 2.74 5.47 8.21 10.95 13.68 16.42 19.16 21.89 24.63 27.34 30.11 32.84 35.58 38.32 41.05 43.79 46.53 49.26 52.00 54.74 60.21 65.68 68.42 71.16 76.63 82.11 87.58 93.O5 95.79 98.53 104.O0 109.47 123.16 | 3.65 7.30 10.95 14.60 18.25 21.89 25.54 29.19 32.84 36.49 40.14 43.79 47.44 51.O9 54.74 58.39 62.04 65.68 69.33 72.98 80.28 87.58 91.23 94.88 102.18 109.47 116.77 124.07 127.72 131.37 138.67 145.96 164.21 | 4.56 9.12 13.68 18.25 22.81 27.37 31.93 36.49 41.O5 45.61 50.18 54.74 59.30 63.86 68.42 72.98 77.54 82.1l 86.67 91.23 100.35 109.47 114.04 118.60 127.72 136.84 145.97 155.O9 159.65 164.21 173.33 182.46 205.26 | 5.47 10.95 16.42 21.89 27.37 32.84 38.32 43.79 49.26 54.74 60.21 65.68 71.16 76.63 82.11 87.58 93.O5 98.53 104.00 109.47 120.42 131.37 136.84 142.32 153.26 164.21 175.16 186.11 191.58 197.05 208.00 218.95 246.32 | 7.30 14.60 21.89 29.19 36.49 43.79 51.09 58.39 65.68 72.98 80.28 87.58 94.88 102.18 109.47 116.77 124.O7 131.37 138.67 145.97 160.56 175.16 182.46 189.76 204.35 218.95 233.54 248.14 255.44 262.74 277.33 291.93 328.42 | 9.12 18.25 27.37 36.49 45.61 54.74 63.86 72.98 82.1l 91.23 100.35 109.47 118.69 127.72 136.84 145.97 155.O9 164.21 173.33 182.46 200.70 218.95 228.07 237.19 255.44 273.68 291.93 310.18 319.30 328.42 346.67 364.91 410.53 | 10.95 21.89 32.84 43.79 54.74 65.68 76.63 87.58 98.53 109.47 120.42 131.37 142.32 153.26 164.21 175.16 186.11 197.05 208.OO 218.95 240.84 262.74 273.69 284.63 306.53 328.42 350.32 372.21 383.16 394.11 416.00 437.90 492.63 |
表5-7镀银层电流效率100%时的镀层厚度 /μm 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.O | 2.5 | 3.0 | 3.5 | 4.0 | 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 22 24 25 26 28 30 32 34 35 36 38 40 45 | 0.32 0.64 0.96 1.28 l-60 1.92 2.24 2.56 2.87 3.19 3.51 3.83 4.15 4.47 4.79 5.11 5.43 5.75 6.07 6.39 7.O3 7.67 7.99 8.30 8.94 9.58 10.22 10.86 11.18 11.50 12.14 12.78 14.37 | 0.64 1.28 1.92 2.56 3.19 3.83 4.47 5.11 5.75 6.39 7.O3 7.67 8.30 8.94 9.58 10.22 10.86 11.50 12.14 12.78 14.O5 15.33 15.97 16.61 17.89 19.17 20.44 21.72 22.36 23.00 24.28 25.55 28.75 | 0.96 1.92 2.87 3.83 4.79 5.75 6.71 7.67 8.62 9.58 10.54 11.50 12.46 13.42 14.37 15.33 16.29 17.25 18.21 19.17 21.O8 23.00 23.96 24.91 26.83 28.75 30.66 32.58 33.54 34.50 36.41 38.33 43.12 | 1.28 2.56 3.83 5.11 6.39 7.67 8.94 10.22 11.50 12.78 14.O5 15.33 16.61 17.89 19.17 20.44 21.72 23.O0 24.28 25.55 28.11 30.66 31.94 33.22 35.77 38.33 40.89 43.44 44.72 46.O0 48.55 51.11 57.50 | 1.60 3.19 4.79 6.39 7.99 9.58 11.18 12.78 14.37 15.97 17.57 19.17 20.76 22.36 23.96 25.55 27.15 28.75 30.34 31.94 35.14 38.33 39.93 41.52 44.72 47.91 51.11 54.30 55.90 57.50 60.69 63.88 71.87 | 1.92 3.83 5.75 7.67 9.58 11.50 13.42 15.33 17.25 19.17 21.O8 23.O0 24.91 26.83 28.75 30.66 32.58 34.50 36.41 38.33 42.16 46.OO 47.91 49.83 53.66 57.50 61.33 65.16 67.O8 68.99 72.83 76.66 86.24 | 2.24 4.47 6.71 8.94 11-18 13.42 15.62 17.89 20.12 22.36 24.60 26.83 29.70 31.30 33.54 35.77 38.Ol 40.25 42.48 44.72 49.19 53.66 55.90 58.13 62.6l 67.O8 71.55 76.O2 78.26 80.49 84.96 89.44 100.62 | 2.56 5.11 7.67 10.22 12.78 15.33 17.89 20.44 23.00 25.55 28.11 30.66 33.22 35.77 38.33 40.89 43.44 46.O0 48.55 51.11 56.22 61.33 63.89 66.44 71.55 76.66 81.77 86.88 89.44 91.99 97.10 102.21 114.99 |
表5-8镀银层电流效率100%时的镀层质量 /g·m-2 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.0 | 2.5 | 3.0 | 3.5 | 4.O | 1 2 3 4 | 3.35 6.71 10.O6 13.42 | 6.71 13.42 20.12 26.83 | 10.06 20.12 30.18 40.25 | 13.42 26.83 40.25 53.66 | 16.77 33.54 50.31 67.08 | 20.12 40.25 60.37 80.49 | 23.48 46.95 70.43 93.91 | 26.83 53.66 80.49 107.32 |
续表 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.0 | 2.5 | 3.O | 3.5 | 4.0 | 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 22 24 25 26 28 30 32 34 35 36 38 40 45 | 16.77 20.12 23.48 26.83 30.18 33.54 36.89 40.25 43.60 46.95 50.3l 53.66 57.01 60.37 63.72 67.O8 73.78 80.49 83.84 87.20 93.91 100.61 107.32 114.O3 117.38 120.74 127.44 134.15 150.92 | 33.54 40.25 46.95 53.66 60.37 67.08 73.78 80.49 87.20 93.91 100.61 107.32 114.O3 120.74 127.44 134.15 147.57 160.98 167.69 174.40 i87.81 201.23 214.64 228.06 234.76 241.47 254.89 268.30 301.84 | 50.31 60.31 70.43 80.49 90.55 100.61 110.61 120.74 130.80 140.86 150.92 160.98 171.04 181.10 191.16 201.23 221-35 241.47 251.53 261.59 281.7Z 301.84 321.96 342.O8 352.15 362.21 382.33 402.45 452.76 | 67.08 80.49 93.91 107.32 120.74 134.15 147.57 160.98 174.40 187.81 201.23 214.64 228.06 241.47 254.89 268.30 295.13 321.96 335.38 348.79 375.62 402.45 429.28 456.11 469.53 482.92 509.77 536.60 603.68 | 83.84 100.61 117.38 134.15 150.92 167.69 184.46 201.23 218.O0 234.76 251.53 268.30 285.07 301.84 318.61 335.38 368.92 402.45 419.22 435.99 469.53 503.07 536.60 570.14 586.91 603.68 637.22 670.76 754.60 | 100.6l 120.74 140.86 160.98 181.10 201.23 221.35 241.46 261.60 281.72 301.84 321.96 342.09 362.21 382.33 402.45 442.70 482.94 503.07 523.19 563.44 603.68 643.93 684.17 704.29 724.42 764.66 804.91 905.52 | 117.38 140.86 164.34 187.81 211.29 234.77 258.24 281.72 305.19 328.67 352.15 375.62 399.10 422.58 466.05 469.53 516.48 563.44 586.9l 610.39 657.34 704.30 751.25 798.20 821.68 845.15 892.11 939.06 1056.44 | 134.15 160.98 187.81 214.64 241.47 268.30 295.13 321.96 348.79 375.62 402.45 429.28 456.11 482.94 509.77 536.60 590.26 643.92 670.76 697.59 751.25 804.91 858.57 912.23 939.06 965.89 1019.2 1073.2 1207.36 |
表5-9酸性镀锡电流效率l00%时的镀层厚度 /μm 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.0 | 2.5 | 3.O | 3.5 | 4.0 | 1 2 3 4 5 6 | 0.25 0.51 0.76 1.01 1.27 1.52 | 0.51 1.01 1.52 2.03 2.53 3.04 | 0.76 1.52 2.28 3.04 3.80 4.56 | 1.01 3.O2 3.04 4.06 5.O7 6.O8 | 1.27 2.53 3.80 5.07 6.34 7.60 | 1.52 3.04 4.56 6.O8 7.60 9.12 | 2.O3 4.06 6.O8 8.1l 10.14 12.17 | 2.53 5.07 7.60 10.14 12.67 15.21 |
续表 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.0 | 2.5 | 3.O | 3.5 | 4.O | 7 8 9 10 11 12 13 14 15 16 17 18 19 20 22 24 25 26 28 30 32 34 35 36 38 40 45 | 1.77 2.O3 2.28 2.53 2.79 3.04 3.29 3.55 3.80 4.06 4.31 4.56 4.82 5.07 5.58 6.08 6.34 6.59 7.10 7.60 8.11 8.62 8.87 9.12 9.63 10.14 11.40 | 3.55 4.06 4.56 5.07 5.58 6.08 6.59 7.10 7.60 8.11 8.62 9.12 9.63 10.14 11.15 12.17 12.67 13.18 14.19 15.21 16.22 17.23 17.74 18.25 19.26 20.28 22.81 | 5.32 6.O8 6.84 7.60 8.36 9.12 9.88 10.64 11.40 12.17 12.93 13.69 14.45 15.21 16.73 18.25 19.01 19.77 21.29 22.81 24.33 25.85 26.6l 27.37 28.89 30.41 34.21 | 7.10 8.1l 9.12 10.14 11.15 12.17 13.18 14.19 15.21 16.22 17.23 18.25 19.26 20.28 22.30 24.33 25.34 26.36 28.39 30.41 32.44 34.47 35.48 36.50 38.52 40.55 45.62 | 8.87 10.14 11.40 12.67 13.94 15.21 16.47 17.74 19.Ol 20.28 21.54 22.81 24.O8 25.34 27.88 30.41 31.68 32.95 35.48 38.O2 40.55 43.O9 44.35 45.62 48.15 50.69 57.02 | 10.64 12.17 13.69 15.21 16.73 18.25 19.77 21.29 22.81 24.33 25.85 27.37 28.89 30.41 33.45 36.50 38.02 39.54 42.58 45.62 48.66 51.70 53.22 54.74 57.79 60.83 68.43 | 14.19 16.22 18.25 20.28 22.30 24.33 26.36 28.39 30.41 32.44 34.47 36.50 38.52 40.55 44.61 48.66 50.69 57.72 56.77 60.83 64.88 68.94 70.96 72.99 77.O5 81.10 91.24 | 17.74 20.28 22.81 25.34 27.88 30.41 32.95 35.48 38.02 40.55 43.O9 45.62 48.15 50.69 55.76 60.83 63.36 65.90 70.96 76.O3 81.10 86.17 88.71 91.24 96.31 101.38 114.05 |
表5-10酸性镀锡电流效率l00%时的镀层质量 /9·m-2 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.O | 2.5 | 3.0 | 3.5 | 4.O | 1 2 3 4 5 6 7 8 | 1.85 3.69 5.54 7.38 9.23 11.O7 12.92 14.76 | 3.69 7.38 11.07 14.76 18.45 22.14 25.83 29.52 | 5.54 11.07 16.61 22.14 27.68 33.21 38.75 44.28 | 7.38 14.76 22.14 29.52 36.90 44.28 51.60 59.04 | 9.23 18.45 27.68 36.90 46.13 55.35 64.58 73.80 | 11.07 22.14 33.21 44.28 55.35 66.42 77.49 88.56 | 14.76 29.52 44.28 59.04 73.80 88.56 103.32 118.O8 | 18.45 36.90 55.35 73.80 92.25 110.70 129.16 147.61 |
续表 电流密度 A·dm-2 t/min | 0.5 | 1.0 | 1.5 | 2.O | 2.5 | 3.0 | 3.5 | 4.O | 9 lO 11 12 13 14 15 16 17 18 19 20 22 24 25 26 28 30 32 34 35 36 38 40 45 | 16.61 18.45 20.30 22.14 23.99 25.83 27.68 29.52 31_37 33.2l 35.O6 36.90 40.59 44.28 46.13 47.97 51_66 55.35 59.04 62.73 64.58 66.42 70.11 73.80 83.03 | 33.21 36.90 40.59 44.28 47.97 51.66 55.35 59.04 62.73 66.42 70.11 73.80 81.18 88.56 92.25 95.94 103.32 110.70 118.O8 125.47 129.16 132.85 140.23 147.61 166.O6 | 49.82 55.35 60.89 66.42 71.96 77.49 33.O3 88.56 94.10 99.63 105.17 110.70 121.78 132.85 138.38 143.92 154.99 166.O6 177.13 188.20 193.73 199.27 210.34 221.41 249.09 | 66.42 73.80 81.18 88.56 95.94 103.32 110.70 118.O8 125.47 132.85 140.23 147.61 162.37 177.12 184.51 191.89 206.65 221.41 236.17 250.93 258.31 265.69 280.45 295.21 332.11 | 83.O3 92.25 101.48 110.70 119.93 129.16 138.38 147.61 156.83 166.O6 175.28 184.51 202.96 221.41 230.63 239.86 258.31 276.76 295.21 313.66 322.89 322.11 350.56 369.O2 415.14 | 99.63 110.71 121.78 132.85 143.92 154.99 166.O6 177.13 188.20 199.27 210.34 221.41 243.55 265.69 276.76 287.83 309.97 332.12 354.26 376.40 387.47 398.54 420.68 442.82 498.17 | 132.85 147.61 162.37 177.13 191.89 206.65 221.41 236.17 250.93 265.69 280.45 295.2l 324.73 354.25 369.O2 383.78 413.30 442.82 472.34 501.86 516.62 531.38 560.90 590.42 664.23 | 166.06 184.51 202.96 221.41 239.86 258.31 276.76 295.21 313.66 332.11 350.57 369.02 405.92 442.82 461.27 479.72 516.62 553.52 590.43 627.33 645.78 644.23 701.13 738.03 830.29 |
表5-11 碱性镀锡电流效率l00%时的镀层厚度 /μm 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.0 | 2.5 | 3.O | 3.5 | 4.O | 1 2 3 4 5 6 7 8 9 10 | 0.13 0.25 0.38 0.51 0.63 0.76 0.89 1.Ol 1.14 1.27 | 0.25 0.51 0.76 1.01 1.27 1.52 1.77 2.03 2.28 2.53 | 0.38 0.76 1.14 1.52 1.90 2.28 2.66 3.04 3.42 3.80 | 0.51 1.Ol 1.52 2.03 2.53 3.04 3.55 4.O5 4.56 5.07 | 0.63 1.27 1.90 2.53 3.17 3.80 4.44 5.07 5.70 6.34 | 0.76 1.52 2.28 3.04 3.80 4.56 5.32 6.O8 6.84 7.60 | 0.99 1.98 2.97 3.95 4.94 5.93 6.92 7.91 8.90 9.88 | 1.27 2.53 3.80 5.O7 6.34 7.60 8.87 10.14 11.40 12.67 |
续表 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.O | 2.5 | 3.O | 3.5 | 4.0 | 11 12 13 14 15 16 17 18 19 20 22 24 25 26 28 30 32 34 35 36 38 40 45 | 1.39 1.52 1.65 1.77 1.90 2.O2 2.15 2.28 2.41 2.53 2.79 3.04 3.17 3.29 3.55 3.80 4.05 4.31 4.44 4.56 4.82 5.07 5.70 | 2.97 3.04 3.29 3.55 3.80 4.05 4.31 4.56 4.82 5.07 5.58 6.O8 6.34 6.59 7.10 7.60 8.11 8.62 8.87 9.12 9.63 10,14 11.40 | 4.18 4.56 4.94 5.32 5.70 6.08 6.46 6.84 7.22 7.60 8.36 9.12 9.50 9.88 10.64 11.40 12.16 12.93 13.31 13.69 14.45 15.21 17.11 | 5.58 6.08 6.59 7.10 7.60 8.11 8.62 9.12 9.63 10.14 11.15 12.16 12.67 13.18 14.19 15.21 16.22 17.23 17.74 18.25 19.26 20.27 22.81 | 6.97 7.60 8.24 8.87 9.50 10.14 10.77 11.40 12.04 16.67 13.94 15.21 15.84 16.47 17.74 19.Ol 20.27 21.54 22.18 22.81 24.O8 25.34 28.51 | 8.36 9.12 9.88 10.64 11.40 12.16 12.93 13.69 14.45 15.21 16.73 18.25 19.Ol 19.77 21.29 22.81 24.33 25.85 26.61 27.37 28.89 30.41 34.21 | 10.87 11.86 12.85 13.84 14.83 15.81 16.80 17.79 18.78 19.77 21.74 23.72 24.71 25.70 27.68 29.65 31.63 33.61 34.59 35.58 37.56 39.54 44.48 | 13.94 15.21 16.47 17.74 19.0l 20.27 21.54 22.81 24.O8 25.34 27.88 30.41 31.68 32.95 35.48 38.O2 40.55 43.O8 44.35 45.62 48.15 50.69 57.O2 |
表5-12碱性镀锡电流效率l00%时的镀层质量 /g·m-2 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.0 | 2.5 | 3.O | 3.5 | 4.O | 1 2 3 4 5 6 7 8 9 10 11 12 | 0.92 1.85 2.77 3.69 4.61 5.54 6.46 7.38 8.30 9.23 10.15 11.07 | 1.85 3.69 5.54 7.38 9.23 11.O7 12.92 14.76 16.61 18.45 20.30 22.14 | 2.77 5.54 8.30 11.O7 13.84 16.61 19.37 22.14 24.91 27.68 30.45 33.21 | 3.69 7.38 11.O7 14.76 18.45 22.14 25.83 29.52 33.21 36.90 40.59 44.28 | 4.61 9.23 13.84 18.45 23.06 27.68 32.29 36.90 41.42 46.13 50.74 55.36 | 5.54 11.07 16.61 22.14 27.68 33.21 38.75 44.28 49.82 55.36 60.89 66,43 | 7.38 14.76 22.14 29.52 36.90 44.28 51.66 59.05 66.43 73.81 81.19 88.57 | 9.23 18.45 27.68 36.90 46.13 55.36 64.58 73.81 83.03 92.26 101.48 110.71 |
续表 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.O | 2.5 | 3.O | 3.5 | 4.0 | 13 14 15 16 17 18 19 20 22 24 25 26 28 30 32 34 35 36 38 40 45 | 11.99 12.92 13.84 147.76 15.58 16.61 17.53 18.45 20.30 22.14 23.06 23.99 25.83 27.68 29.52 31.37 32.29 33.21 35.O6 36.90 41.52 | 23.99 25.83 27.68 29.52 31.37 33.21 35.O6 36.90 40.59 44.28 46.13 47.97 51.66 55.36 59.05 62.74 64.58 66.43 70.12 73.81 83.03 | 35.98 38.75 41.52 44.28 47.05 49.82 52.59 55.34 60.89 66.43 69.19 71.96 77.50 83.O3 88.57 94.10 96.87 99.64 105.17 110.71 124.55 | 47.97 51.66 55.36 59.O5 62.74 66.43 70.12 73.8l 81.19 88.57 92.26 95.95 103.33 110.71 118.O9 125.47 129.16 132.85 140.23 147.61 166.07 | 59.97 64.58 69.19 73.81 78.42 83.O3 87.65 92.26 101.48 110.71 115.32 119.94 129.16 138.39 147.61 156.84 161.45 166.07 175.29 184.52 207.58 | 71.96 77.50 83.O3 88.57 94.10 99.64 105.17 110.71 121.78 132.85 138.39 143.92 154.99 166.O7 177.14 188.21 193.74 199.28 210.35 221.42 249.10 | 95.95 103.33 110.71 118.O9 125.47 132.85 140.23 147.6l 162.37 177.13 184.52 191.90 206.66 221.42 236.18 250.94 258.32 265.70 280.47 295.23 332.13 | 119.94 129.16 138.39 147.61 156.84 166.07 175.29 184.52 202.97 221.42 230.65 239.87 258.32 276.78 295.23 313.68 322.90 332.13 350.82 369.O3 415.16 |
表5-l3镀锌层电流效率100%时的镀层厚度 /μm 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.O | 2.5 | 3.O | 3.5 | 4.0 | 1 2 3 4 5 6 7 8 9 10 ll 12 13 14 | 0.29 0.57 0.86 1.14 1.43 1.71 2.O0 2.28 2.57 2.85 3.14 3.42 3.71 3.99 | 0.43 0.86 1.28 1.71 2.14 2.57 2.99 3.42 3.85 4.28 4.70 5.13 5.56 5.99 | 0.57 1.14 1.71 2.28 2.85 3.42 3.99 4.56 5.13 5.70 6.27 6.84 7.41 7.98 | 0.71 1.43 2.14 2.85 3.56 4.28 4.99 5.70 6.41 7.13 7.84 8.55 9.26 9.98 | 0.86 1.71 2.57 3.42 4.28 5.13 5.99 6.84 7.70 8.55 9.41 10.26 11.12 11.97 | 1.14 2.28 3.42 4.56 5.70 6.84 7.98 9.12 10.26 11.40 12.54 13.68 14.82 15.96 | 1.43 2.85 4.28 5.70 7.13 8.55 9.98 11.40 12.83 14.25 15.68 17.10 18.53 19.95 | 1.71 3.42 5.13 6.84 8.55 10.26 11.97 13.68 15.39 17.10 18.8l 20.52 22.24 23.95 |
续表 电流密度 A·dm-2 t/min | 0.5 | 1.0 | 1.5 | 2.0 | 2.5 | 3.0 | 3.5 | 4.0 | 15 16 17 18 19 20 22 24 25 26 28 30 32 34 35 36 38 40 45 | 4.28 4.56 4.85 5.13 5.42 5.70 6.27 6.84 7.13 7.41 7.98 8.55 9.12 9.69 9.98 10.26 10.83 11.40 12.83 | 6.41 6.84 7.27 7.70 8.12 8.55 9.41 10.26 10.69 11.12 11.97 12.83 13.68 14.54 14.97 15.39 16.25 17.10 19.24 | 8.55 9.12 9.69 10.26 10.83 11.40 12.54 13.68 14.25 14.82 15.96 17.10 18.24 19.38 19.95 20.52 21.67 22.81 25.66 | 10.69 11.40 12.12 12.83 13.54 14.25 15.68 17.10 17.82 18.53 19.95 21.38 22.81 24.23 24.94 25.66 27.08 28.51 32.O2 | 12.83 13.68 14.54 15.39 16.25 17.10 18.81 20.52 21.38 22.24 23.95 25.66 27.37 29.O8 29.93 30.79 32.50 34.21 38.48 | 17.10 18.24 19.38 20.52 21.67 22.8l 25.09 27.37 28.51 29.65 31.93 34.21 36.49 38.77 39.91 41.O5 43.33 45.61 51.31 | 21.38 22.81 24.23 25.66 27.08 28.51 31.36 34.21 35.63 37.O6 39.91 42.76 45.6l 48.46 49.89 51.3l 54.16 57.01 64.14 | 25.66 27.37 29.O8 30.79 32.50 34.2l 37.63 41.05 42.76 44.47 47.89 51.31 54.73 58.15 59.86 61.57 65.O0 68.42 76.97 |
表5-14镀锌层电流效率100%时的镀层质量 /g·m-2 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.0 | 2.5 | 3.O | 3.5 | 4.O | 1 2 3 4 5 6 7 8 9 10 ll 12 13 14 15 16 | 2.O3 4.07 6.10 8.13 10.16 12.20 14.23 16.26 18.29 20.33 22.36 24.39 26.42 28.46 30.49 32.52 | 3.O5 6.10 9.15 12.20 15.24 18.29 21.34 24.39 27.44 30.49 33.54 36.59 39.63 42.68 45.73 48.78 | 4.07 8.13 12.20 16.26 20.33 24.39 28.46 32.52 36.59 40.65 44.72 48.78 52.85 56.91 60.98 65.04 | 5.08 10.16 15.24 20.33 25.41 30.49 35.57 40.65 45.73 50.81 55.89 60.98 66.O6 71.14 76.22 81.30 | 6.10 12.20 18.29 24.39 30.49 36.59 42.68 48.78 ‘54.88 60.98 67.07 73.17 79.27 85.37 91.46 97.56 | 8.13 16.26 24.39 35.52 40.65 48.78 56.91 65.04 73.17 81.30 89.43 97.56 105.69 113.82 121.95 130.O8 | 10.16 20.33 30.49 40.65 50.8l 60.98 71.14 81.30 91.46 101.63 111.79 121.95 132.12 142.28 152.44 162.60 | 12.20 24.39 36.59 48.78 60.98 73.17 85.37 97.56 109.76 121.95 134.15 146.34 158.54 170.73 182.93 195.12 |
续表 电流密度 A·dm-2 t/min | 0.5 | 1.O | 1.5 | 2.O | 2.5 | 3.0 | 3.5 | 4.O | 17 18 19 20 22 24 25 26 28 30 32 34 35 36 38 40 45 | 34.55 36.59 38.62 40.65 44.72 48.78 50.81 52.85 56.91 60.98 65.04 69.11 71.14 73.17 77.24 81.30 91.46 | 51.38 54.88 57.93 60.98 67.07 73.17 76.22 79.27 85.37 91.46 97.56 103.66 106.71 109.76 115.85 121.95 137.20 | 69.11 73.17 77.24 81.30 89.43 97.56 101.63 105.69 113.82 121.95 130.O8 138.21 142.28 146.34 154.47 162.60 182.93 | 86.38 91.46 96.55 101.63 111.79 121.03 127.03 132.11 142.28 152.44 162.60 172.77 177.85 182.93 193.O9 203.25 228.66 | 103.66 109.76 115.85 121.95 134.15 146.34 152.44 158.54 170.73 182.93 195.12 207.32 213.42 219.51 231.71 243.90 274.39 | 138.21 146.34 154.47 162.60 178.86 195.12 203.25 211.38 227.64 243.90 260.16 276.42 284.55 292.68 308.94 325.20 365.86 | 172.77 182.93 193.09 203.25 223.58 243.90 254.07 264.23 284.56 304.88 325.21 345.53 355.69 365.86 386.18 406.51 457.32 | 207.32 219.51 231.71 243.90 268.29 292.68 304.88 317.08 341.47 365.86 390.25 414.64 426.83 439.03 463.42 487.81 548.78 |
表5-15 氰化镀黄铜(70%铜、30%锌)电流效率l00%时的镀层厚度 /μm 电流密度 A·dm-2 t/min | 0.3 | 0.5 | 1.O | 1.5 | 2.0 | 2.5 | 3.0 | 4.0 | 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 | 0.07 0.13 0.20 0.26 0.33 0.40 0.46 0.53 0.59 0.66 0.73 0.79 0.86 0.92 0.99 1.06 1.12 1.19 | 0.11 0.22 0.33 0.44 0.55 0.66 0.77 0.88 0.99 1.10 1.21 1.32 1.43 1.54 1.65 1.76 1.87 1.98 | 0.22 0.44 0.66 0.88 1.10 1.32 1.54 1_76 1.98 2.20 2.42 2.64 2.86 3.08 3.30 3.52 3.74 3.96 | 0.33 0.66 0.99 1.32 1.65 1.98 2.31 2.64 2.97 3.30 3.63 3.96 4.29 4.62 4.95 5.28 5.61 5.94 | 0.44 0.88 1.32 1.76 2.20 2.64 3.O8 3.52 3.96 4.40 4.84 5.28 5.72 6.16 6.60 7.04 7.48 7.92 | 0.55 1.10 1.65 2.20 2.75 3.30 3.85 4.40 4.95 5.50 6.O5 6.60 7.15 7.70 8.25 8.80 9.35 9.90 | 0.66 1.32 1.98 2.64 3.30 3.96 4.62 5.28 5.94 6.60 7.26 7.92 8.58 9.24 9.90 10.56 11.21 11.87 | 0.88 1.76 2.64 3.52 4.40 5.38 6.16 7.04 7.92 8.80 9.68 10.56 11.43 12.31 13.19 14.07 14.95 15.83 |
续表 电流密度 A·dm-2 t/min | 0.3 | 0.5 | 1.O | 1.5 | 2.O | 2.5 | 3.O | 4.O | 19 20 22 24 25 26 28 30 32 34 35 36 38 40 45 | 1.25 1.32 1.45 1.58 1.65 1_72 1.85 1.98 2.11 2.24 2.31 2.37 2.51 2.64 2.97 | 2.O9 2.20 2.42 2.64 2.75 2.86 3.O8 3.30 3.52 3.74 3.85 3.95 4.18 4.40 4.95 | 4.18 4.40 4.84 5.28 5.50 5.72 6.16 6.60 7.04 7.48 7.70 7.92 8.36 8.80 9.90 | 6.27 6.60 7.26 7.92 8.25 8.58 9.24 9.90 10.56 11.21 11.54 11.87 12.53 13.19 14.84 | 8.36 8.80 9.68 10.56 10.99 11.43 12.31 13.19 14.07 14.95 15.39 15.83 16.71 17.59 19.79 | 10.45 10.99 12.O9 13.19 13.74 14.29 15.39 16.49 17.59 18.69 19.24 19.79 20.89 21.99 24.74 | 12.53 13.19 14.51 15.83 16.49 17.15 18.47 19.79 21.11 22.43 23.O9 23.75 25.O7 26.39 29.69 | 16.71 17.59 19.35 21.11 21_99 22.87 24.63 26.39 28.15 29.91 30.79 31.67 33.42 35.18 39.58 |
表5-l6 氰化镀黄铜(70%铜、30%锌)电流效率l00%时的镀层质量 /g·m-2 电流密度 A·dm-2 t/min | 1.0 | 1.5 | 2.O | 2.5 | 3.0 | 3.5 | 4.O | 5.O | 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 | 0.55 1.11 1.66 2.22 2.77 3.32 3.88 4.43 4.99 5.54 6.10 6.65 7.20 7.76 8.31 8.87 9.42 9.97 10.53 | 0.92 1.85 2,77 3.69 4.62 5.54 6.46 7.39 8.31 9.24 10.16 11.O8 12.Ol 12.93 13.85 14.78 15.79 16.62 17.55 | 1.85 3.69 5.54 7.39 9.24 11.O8 12.93 14.78 16.62 18.47 20.32 22.17 24.O1 25.86 27.71 29.55 31.40 33.25 35.10 | 2.77 5.54 8.31 11.O8 13.85 16.62 19.39 22.17 24.94 27.71 30.48 33.25 36.O2 38.79 41.56 44.33 47.10 49.87 52.64 | 3.69 7.39 11.O8 14.78 18.47 22.17 25.86 29.55 33.25 36.94 40.64 44.33 48.03 51.72 55.41 59.11 62.80 66.50 70.19 | 4.62 9.24 13.85 18.47 23.09 27.71 32.32 36.94 41.56 46.18 50.80 55.41 60.O3 64.65 69.27 73.89 78.50 83.12 87.74 | 5.54 11.08 16.62 22.17 27.71 33.25 38.79 44.33 49.87 55.41 60.96 66.50 72.04 77.58 83.12 88.66 94.20 99.75 105.29 | 7.39 14.78 Z2.17 29.55 36.94 44.33 51.72 59.11 66.50 73.89 81.27 88.66 96.O5 103.44 110.83 118.22 125.60 132.99 140.38 |
续表 电流密度 A·dm-2 t/min | 0.3 | 0.5 | 1.O | 1.5 | 2.O | 2.5 | 3.O | 4.O | 19 20 22 24 25 26 28 30 32 34 35 36 38 40 45 | 1.25 1.32 1.45 1.58 1.65 1.72 1.85 1.98 2.11 2.24 2.31 2.37 2.51 2.64 2.97 | 2.09 2.20 2.42 2.64 2.75 2.86 3.08 3.30 3.52 3.74 3.85 3.95 4.18 4.40 4.95 | 4.18 4.40 4.84 5.28 5.50 5.72 6.16 6.60 7.04 7.48 7.70 7.92 8.36 8.80 9.90 | 6.27 6.60 7.26 7.92 8.25 8.58 9.24 9.90 10.56 11.21 11.54 11.87 12.53 13.19 14.84 | 8.36 8.80 9.68 10.56 10.99 11.43 12.31 13.19 14.O7 14.95 15.39 15.83 16.71 17.59 19.79 | 10.45 10.99 12.O9 13.19 13.74 14.29 15.39 16.49 17.59 18.69 19.24 19.79 20.89 21.99 24.74 | 12.53 13.19 14.51 15.83 16.49 17.15 18.47 19.79 21.11 22.43 23.O9 23.75 25.07 26.39 29.69 | 16.71 17.59 19.35 21.11 21.99 22.87 24.63 26.39 28.15 29.91 30.79 31.67 33.42 35.18 39.58 |
表5-l6 氰化镀黄铜(70%铜、30%锌)电流效率l00%时的镀层质量 /g·m-2 电流密度 A·dm-2 t/min | 1.0 | 1.5 | 2.0 | 2.5 | 3.O | 3.5 | 4.0 | 5.0 | 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 | 0.55 1.11 1.66 2.22 2.77 3.32 3.88 4.43 4.99 5.54 6.10 6.65 7.20 7.76 8.31 8.87 9.42 9.97 10.53 | 0.92 1.85 2.77 3.69 4.62 5.54 6.46 7.39 8.31 9.24 10.16 11.O8 12.Ol 12.93 13.85 14.78 15.79 16.62 17.55 | 1.85 3.69 5.54 7.39 9.24 11.08 12.93 14.78 16.62 18.47 20.32 22.17 24.Ol 25.86 27.71 29.55 31.40 33.25 35.10 | 2.77 5.54 8.3l 11.08 13.85 16.62 19.39 22.17 24.94 27.71 30.48 33.25 36.O2 38.79 41.56 44.33 47.10 49.87 52.64 | 3.69 7.39 11.O8 14.78 18.47 22.17 25.86 29.55 33.25 36.94 40.64 44.33 48.O3 51.72 55.41 59.1l 62.80 66.50 70.19 | 4.62 9.24 13.85 18.47 23.09 27.71 32.32 36.94 41.56 46.18 50.80 55.41 60.O3 64.65 69.27 73.89 78.50 83.12 87.74 | 5.54 11.O8 16.62 22.17 27.71 33.25 38.79 44.33 49.87 55.41 60.96 66.50 72.04 77.58 83.12 88.66 94.20 99.75 105.29 | 7.39 14.78 22.17 29.55 36.94 44.33 51.72 59.11 66.50 73.89 81.27 88.66 96.O5 103.44 110.83 118.22 125.60 132.99 140.38 |
续表 电流密度 A·dm-2 t/min | 1.O | 1.5 | 2.O | 2.5 | 3.0 | 3.5 | 4.0 | 5.0 | 20 22 24 25 26 . 28 30 32 34 35 36 38 40 45 | 11.O8 12.19 13.30 13.85 14.41 15.52 16.62 17.73 18.84 19.39 19.95 21.06 22.17 24.94 | 18.47 20.32 22.17 23.09 24.01 25.86 27.71 29.55 31.40 32.32 33.25 35.10 36.94 41.56 | 36.94 40.64 44.33 46.18 48.O3 51.72 55.41 59.11 62.80 64.65 66.50 70.16 73.89 83.12 | 55.4l 60.96 66.50 69.27 72.04 77.58 83.12 88.66 94.20 96.97 99.75 105.29 110.83 124.68 | 73.89 81.27 88.66 92.36 96.O5 103.44 110.83 118.22 125.60 129.30 132.99 140.38 147.77 166.24 | 92.36 101.59 110.83 115.45 120.O6 129.30 138.53 147.77 157.O1 161.62 166.24 175.48 184.71 207.80 | 110.83 212.91 132.99 138.53 144.08 155.16 166.24 177.32 188.41 193.95 199.49 210.57 221.66 249.36 | 147.77 162.55 177.32 184.71 192.10 206.88 221.66 236.43 251.2l 258.60 265.99 280.76 295.54 332.48 |
表5-17氰化镀青铜(90%铜、10%锡)电流效率l00%时的镀层厚度 /μm 电流密度 A·dm-2 t/min | 1.0 | 1.5 | 2.0 | 2.5 | 3.O | 3.3 | 4.0 | 5.O | 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 22 | 0.40 0.81 1.21 1.62 2.O2 2.43 2.83 3.24 3.64 4.04 4.45 4.85 5,26 5.66 6.07 6.47 6.88 7.28 7.68 8.09 8.90 | 0.61 1.21 1.82 2.43 3.O3 3.64 4.25 4.85 5.46 6.07 6.67 7.28 7.89 8.49 9.10 9.7l 10.31 10.92 11.53 12.13 13.35 | 0.81 1.62 2.43 3.24 4.04 4.85 5.66 6.47 7.28 8.O9 8.90 9.71 10.52 11.33 12.13 12.94 13.75 14.56 15.37 16.18 17.80 | 1.Ol 2.O2 3.O3 4.04 5.O6 6.07 7.O8 8.09 9.10 10.11 11.12 12.13 13.15 14.16 15.17 16.18 17.19 18.20 19.21 20.22 22.25 | 1.21 2.43 3.64 4.85 6.07 7.28 8.49 9.71 10.92 12.13 13.35 14.56 15.77 16.98 18.20 19.41 20.62 21.84 23.O5 24.26 26.69 | 1.42 2.83 4.25 5.66 7.O8 8.49 9.91 11.32 12.74 14.15 15.57 16.99 18.40 19.82 21.23 22.65 24.O6 25.48 26.89 28.31 31.14 | 1.62 3.24 4.85 6.47 8.09 9.71 11.13 12.94 14.56 16.18 17.80 19.41 21.O3 22.65 24.27 25.89 27.50 29.12 30.74 32.36 35.59 | 2.02 4.04 6.07 8.09 10.11 12.13 14.16 16.18 18.20 20.22 22.25 24.27 26.29 28.3l 30.34 32.36 34.38 36.40 38.42 40.45 44.49 |
续表 电流密度 A·dm-2 t/min | 1.0 | 1.5 | 2.0 | 2.5 | 3.O | 3.3 | 4.0 | 5.0 | 24 25 26 28 30 32 34 35 36 38 40 45 | 9.71 10.11 10.52 11.33 12.13 12.94 13.75 14.16 14.56 15.37 16.18 18.20 | 14.56 15.17 15.77 16.99 18.20 19.3l 20.63 21.23 21.84 23.O5 24.27 27.30 | 19.41 20.22 21.O3 22.65 24.27 25.89 27.50 28.31 29.12 30.74 32.36 36.40 | 24.27 25.28 26.29 28.31 30.34 32.36 34.38 35.39 36.40 38.42 40.45 45.50 | 29.12 30.33 31.54 33.97 36.40 38.82 41.25 42.46 43.68 46.10 48.53 54.59 | 33.97 35.39 36.80 39.63 42.46 45.29 48.12 49.54 50.96 53.79 56.62 63.69 | 38.83 40.45 42.06 45.30 48.54 51.77 55.01 56.63 58.24 61.48 64.72 72.80 | 48.54 50.56 52.58 56.63 60.67 64.72 68.76 70.78 72.80 76.85 80.89 91.Ol |
表5-l8氰化镀青铜(90%铜、10%锡)电流效率l00%时的镀层质量 /g·m-2 电流密度 A·dm-2 t/min | 1.O | 1.5 | 2.0 | 2.5 | 3.O | 3.3 | 4.O | 5.O | 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 22 24 | 3.49 6.99 10.48 13.98 17.47 20.96 24.46 27.96 31.45 34.95 38.44 41.94 45.43 48.92 52.42 55.91 59.41 62.90 66.40 69.89 76.88 83.87 | 5.24 10.48 15.73 20.97 26.21 31.45 36.69 41.94 47.18 52.42 57.66 62.90 68.14 73.39 78.63 83.87 89.11 94.34 99.60 104.84 115.32 125.81 | 6.99 13.98 20.97 27.96 34.95 41.94 48.92 55.91 62.90 69.89 76.88 83.87 90.86 97.85 104.84 111.83 118.82 125.81 132.80 139.78 153.76 167.74 | 8.74 17.47 26.21 34.95 43.68 52.42 61.16 69.89 78.63 87.37 96.10 104.84 113.58 122.31 131.05 139.78 148.52 157.26 165.99 174.73 192,20 209.68 | 10.48 20.97 31.45 41.94 52.42 62.90 73.39 83.87 94.35 104.84 115.32 125.81 136.29 146.77 157.26 167.74 178.22 188.71 199.19 209.68 230.64 251.61 | 12.23 24.46 36.69 48.92 61.16 73.39 85.62 97.85 110.08 122.31 134.54 146.77 159.01 171.24 183.47 195.70 207.93 220.16 232.39 244.62 269.09 293.55 | 13.98 27.96 41.94 55.91 69.89 83.87 97.85 111.83 125.81 139.79 153.76 167.74 181.72 195.70 209.68 223.66 237.63 251.61 265.59 279.57 307.53 335.48 | 17.47 34.95 52.42 69.98 87.37 104.84 122.31 139.78 157.26 174.73 192.20 209.68 227.15 244.62 262.10 279.57 297.04 314.52 331.99 349.46 384.41 419.35 |
续表 电流密度 A·dm-2 t/min | 1.0 | 1.5 | 2.O | 2.5 | 3.O | 3.3 | 4.O | 5.O | 25 26 28 30 32 34 35 36 38 40 45 | 87.37 90.86 97.85 104.84 111.83 118.82 122.31 125.81 132.80 139.78 157.26 | 131.O5 136.29 146.77 157.26 167.74 178.23 183.47 188.71 199.19 209.68 235.89 | 174.73 181.72 195.70 209.68 223.66 237.63 244.62 251.61 265.59 279.57 314.52 | 218.4l 227.15 244.62 262.10 297.57 297.04 305.78 314.52 331.99 349.46 393.14 | 262.10 272.58 293.55 314.51 335.48 356.45 366.93 377.42 398.38 419.35 471.77 | 305.78 318.01 342.47 366.94 391.40 415.86 428.09 440.32 464.79 489.25 550.40 | 349.46 363.44 391.40 419.36 447.31 475.27 489.25 503.23 531.18 559.14 629.O3 | 436.83 454.30 489.25 524.19 559.14 594.O9 611.56 629.03 663.98 698.92 786.29 |
表5-l9镀层厚度与质量换算表 /g·m-2 厚度/μm | 黄铜 | 青铜 | 铬 | 铜 | 金 | 镍 | 银 | 锡 | 锌 | l | 8.40 | 8.70 | 6.90 | 8.93 | 19.30 | 8.90 | 10.50 | 7.28 | 7.13 | 2 | 16.80 | 17.40 | 13.80 | 17.86 | 38.60 | 17.80 | 21.OO | 14.56 | 14.26 | 3 | 25.20 | 26.10 | 20.70 | 26.79 | 57.90 | 26.70 | 31.50 | 21.84 | 21.39 | 4 | 33.60 | 34.80 | 27.60 | 35.72 | 77.20 | 35.60 | 42.O0 | 29.12 | 28.52 | 5 | 42.00 | 43.50 | 34.50 | 44.65 | 96.50 | 44.50 | 52.50 | 36.40 | 35.65 | 6 | 50.40 | 52.20 | 41.40 | 53.58 | 115.80 | 53.40 | 63.O0 | 43.68 | 42.78 | 7 | 58.80 | 60.90 | 48.30 | 62.51 | 135.10 | 62.30 | 73.50 | 50.96 | 49.91 | 8 | 67.20 | 69.60 | 55.20 | 71.44 | 154.40 | 71.20 | 84.O0 | 58.24 | 57.04 | 9 | 75.60 | 78.30 | 62.10 | 80.37 | 173.70 | 80.10 | 94.50 | 65.52 | 64.17 | 10 | 84.O0 | 87.00 | 69.O0 | 89.30 | 193.OO | 89.00 | 105.O0 | 72.80 | 71.30 | 20 | 168.O0 | 174.O0 | 138.O0 | 178.60 | 386.O0 | 178.00 | 210.O0 | 145.60 | 142.60 | 30 | 252.OO | 261.O0 | 207.O0 | 267.90 | 579.O0 | 267.O0 | 315.O0 | 218.40 | 213.90 | 40 | 336.O0 | 348.O0 | 276.O0 | 357.20 | 772.O0 | 356.O0 | 420.O0 | 291.20 | 285.20 | 50 | 420.O0 | 435.OO | 345.O0 | 446.50 | 965.O0 | 445.O0 | 525.O0 | 364.O0 | 356.50 | 60 | 504.O0 | 522.O0 | 414.O0 | 535.80 | 1158.O0 | 534.O0 | 630.O0 | 435.80 | 427.80 | 70 | 588.O0 | 609.O0 | 483.O0 | 625.10 | 1351.00 | 623.O0 | 735.O0 | 509.60 | 499.10 | 80 | 672.00 | 696.O0 | 552.O0 | 714.40 | 1544.O0 | 712.OO | 840.O0 | 582.40 | 570.40 | 90 | 756.O0 | 783.O0 | 621.OO | 803.70 | 1737.O0 | 801.O0 | 945.O0 | 655.20 | 641.70 | 100 | 840.O0 | 870.O0 | 690.O0 | 893.O0 | 1930.O0 | 890.O0 | 1050.O0 | 728.O0 | 713.00 |
表5-20部分镀液的体积电流密度 镀液名称 | 预镀黄铜 | 镀黄铜 | 氰化镀铜 | 一班制酸铜 | 二班制酸铜 | 氰化镀金 | 硫酸盐镀光亮镍 | D,/(A/L) | 0.1 | 0.6 | 0.6 | 0.4 | 0.25 | 0.1 | 0.7~1 | 镀液名称 | 黑镲 | 氰化镀光亮银 | 酸性镀锡 | 碱性镀锡 | 装饰铬 | 硬铬 | 氰化镀光亮锌 | 硫酸盐镀锌 | 钾盐镀锌 | D,/(A/L) | 0.O5 | 0.3~O.4 | 0.3 | 0.5 | 1.5 | 1.5 | 0.7 | 0.7 | 0.7 | | | | | | | | | | | | | | |
表5-21光亮铬檀电流效率及沉积率(4009/L铬酸,4g/L H2S04) 温度:40℃ 电流密度/(A/dm2) | 8.0 | 12.O | 16.0 | 24.0 | 32.0 | 电流效率/% | 7.1 | 9.8 | 12.0 | 15.3 | 17.8 | 沉积率/(g/h) | 0.18369 | 0.38032 | 0.62093 | 1.18752 | 1.84209 | 沉积率/(g/min) | 0.00306 | 0.00634 | 0.01035 | 0.01878 | 0.03071 | 沉积率/(μm/h) | 2,66217 | 5.51188 | 8.99899 | 17.2105 | 26.6970 | 沉积率/(μm/min) | 0.04437 | 0.O9186 | 0.16998 | 0.28684 | 0.44494 | 沉积率/[g/(A·h)] | 0.02296 | 0.03169 | 0.03881 | 0.04948 | 0.05757 | 沉积率/[g/(A·min)] | 0.00038 | 0.00053 | 0.00065 | 0.00082 | 0.00096 |
温度:45℃ 电流密度/(A/dm2) | 12.O | 16.O | 24.O | 32.O | 48.0 | 电流效率/% | 9.O | 10.3 | 13.4 | 15.5 | 18.3 | 沉积率/(g/h) | 0.34927 | 0.53296 | 1.04005 | 1.60406 | 2.84075 | 沉积率/(g/min) | 0.00582 | 0.00888 | 0.01733 | 0.02673 | 0.04735 | 沉积率/(μm/h) | 5.O6188 | 7.72405 | 15.0733 | 23.2472 | 41.1703 | 沉积率/(μm/min) | 0.08436 | 0.12873 | 0.25116 | 0.38745 | 0.68617 | 沉积率/[g/(A·h)] | 0.02911 | 0.03333 | 0.04334 | 0.05013 | 0.O5918 | 沉积率/[g/(A·min)] | 0.00049 | 0.00055 | 0.00072 | 0.00084 | 0.00099 |
表5-22硬铬槽电流效率及沉积率(2509/L铬酸,2.59/L HzS04) 温度:50℃ 电流密度/(A/dm2) | 16.0 | 24.O | 38.0 | 48.O | 62.O | 电流效率/% | 12.8 | 15.4 | 17.9 | 18.8 | 20.1 | 沉积率/(g/h) | 0.66232 | 1.19529 | 2.19977 | 2.91836 | 4.03021 | 沉积率/(g/mim) | 0.01104 | 0.01992 | 0.03666 | 0.04864 | 0.06717 | 沉积率/(μm/h) | 9.59888 | 17.3265 | 31.8807 | 42.2951 | 58.4088 | 沉积率/(μm/min) | 0.15998 | 0.28878 | 0.53135 | 0.70492 | 0.97348 | 沉积率/[g/(A·h)] | 0.04140 | 0.04980 | 0.05789 | 0.06080 | 0.06500 | 沉积率/[g/(,A·min)] | 0.00070 | 0.00083 | 0.00096 | 0.00101 | 0.O0108 |
续表 温度:55℃ | 电流密度/(A/dm2) | 16.O | 24.O | 38.O | 48.0 | 62.O | 电流效率/% | 10.4 | 14.217.0 | 17.O | 17.5 | 19.1 | 沉积率/(g/h) | 0.53814 | 1.10215 | 2.08916 | 2.71656 | 3.82970 | 沉积率/(g/min) | 0.00897 | 0.Ol837 | 0.03482 | 0.04528 | 0.06383 | 沉积率/(μm/h) | 7.79910 | 15.9731 | 31.2777 | 39.3704 | 55.5029 | 沉积率/(μm/min) | 0.12998 | 0.26622 | 0.52130 | 0.65617 | 0.92505 | 沉积率/[g/(A·h)] | 0.03363 | 0.04592 | 0.05498 | 0.05660 | 0.06177 | 沉积率/[g/(A·min)] | 0.00056 | 0.00077 | 0.00092 | 0.00094 | 0.O0103 |
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